陈艳霞
中国科学技术大学教授
陈艳霞,女,1971年9月出生于湖南省,本科、硕士、博士均毕业于厦门大学,现任中国科学技术大学化学物理系和合肥微尺度物质科学国家实验室教授、博士生导师,主要研究表面电化学、光谱电化学和电催化。
学习和工作经历
1989.9 – 1993.7,厦门大学化学化工学院学士 物理化学专业;
1993.9 – 1995.7,厦门大学化学系,硕士学位,物理化学专业;
1995.9 – 1998.10,厦门大学化学系,博士学位,物理化学专业;
1998.11 – 1999.2,厦门大学化学系,科研助手,物理化学专业;
1999.3 – 2000.12,杜塞尔多夫大学表面和凝固态材料研究所(A. Otto教授),洪堡奖学金,博士后,利用衰减全内反射拉曼光谱研究单晶铜表面物种的吸附,了解表面增强拉曼效应和金属表面粗糙度的关系;
2001.1 – 2001.12,慕尼黑工业大学物理系界面和能量转换研究所(U. Stimming教授),博士后,开发、表征优化氢氧燃料电池直接甲醇燃料电池的膜电极列阵(Membrane Electrode Assemblies),以降低催化剂用量同时提高电池的效率,延长电池的寿命;
2002.1 – 2002.3,北海道大学催化研究中心界面和光谱电化学实验室(M. Osawa教授),日本北海道大学日本文部科学省中核集团机构COE研究员,主要任务:利用表面增强红外光谱研究甲醇在铂电极上的阳极氧化;
2002.4 – 2006.12,乌尔姆大学表面化学和催化研究所 (R. J. Behm教授) 博士后,电化学原位红外光谱和电化学在线质谱研究燃料电池相关的电催化反应;
2007.1 – 至今,中国科技大学化学物理系,合肥微尺度物质科学国家实室,教授,博士生导师,谱学电化学在电催化中的应用。
研究方向
表面电化学、光谱电化学和电催化,着重于电化学界面结构、燃料电池以及生物电化学相关的电催化反应机理动力学的基础研究以及相关研究技术的开发。
在研项目
1.面向车用燃料电池的纳米-介观-宏观多级结构的电催化体系的研究, 973 重大科学研究计划子课题: 结构明确的高活性电催化剂纳米结构基元的合成(编号2015CB932300,2014-2019)
2.Pt系单晶电极上氧还原反应超电势的起源研究, 国家自然基金面上项目 (编号:21473175, 2015-2018)
3. 等离子基元增强拉曼光谱仪器的研发与应用子课题,PERS在电化学基础研究中的应用,国家重大科学仪器设备开发专项(编号:2011YQ03012416 2012-2016)
4. 电化学导数质谱与红外光谱联用技术及其在燃料电池电催化中的应用, 国家自然基金面上项目 (编号:21273215, 2013-2016)
已完成项目
1. 基于分子和分子体系的量子调控子课题,电极过程的量子调控, 973 重大科学研究计划 (编号2010CB923302,2009-2014)
2.台湾中国科技大学海外优秀留学人才启动基金(2007-2009)
3. 在可控的温度及传质下甲醇氧化的电化学原位红外光谱研究, 国家中华人民共和国国家自然科学基金委员会面上项目(项目批准号:20773116, 2008-2010)
4. 低铂担载甲醇氧化电催化剂结构-性能关系研究, 德国洪堡基金会回国后续支持项目(2007-2009)
5. 用于甲醇阳极氧化的低维纳米复合电催化剂的制备及性能表征, 厦门大学固体表面物理国家重点实验室开放课题 (2008-2009)
6. 中国科院百人计划(2009-2011)
7. 石墨烯米粒子的构筑及其电催化活性研究, 厦门大学固体表面物理国家重点实验室开放课题(2010-2011)
8. 谱学电化学在电催化中的应用, 教育部留学回国人员启动基金(2010-2012)
9. 铂基氧还原催化剂性能改善机理研究, 国家中华人民共和国国家自然科学基金委员会面上项目(项目批准号:21073176,2011-2013).
获奖情况
1. 电化学青年奖,中国电化学会,2011.10
2. 青年研究奖学金,德国洪堡基金会, 1999. 7- 2000.12, 2002.7-2002.9
3. 日本文部省COE奖学金
4. 中国科学院星”百人计划”择优支持
5. 北海道大学访问教授
发表的学术论文及专著
Papers published in 2014
1. The Effect of 乙醇 Concentration on the 质量 Signal of CO2 Detected by Differential Mass Spectrometry
Wei Chen; Qian Tao; Jun Cai; Yan Xia Chen
Electrochemistry Communications, 2014,48,10.
2. On the Origin of the Errors of ik as Estimated from K-L Equation in Rotating Disk Electrode System
Wei Chen; Lingwen Liao; Zhengda He; Yanxia Chen
Journal of Electrochemistry
3. The Preparation of Surfactant-free Pt and PtRu Nanoparticles with high Activity for 甲醇 Oxidation
Yao Yao, Jun Cai, Yong Li Zheng, Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2014
4. Methanol Oxidation at Pt and PtRu Electrodes, a Study by Combined in-situ Infrared Spectroscopy and Differential Electrochemical 质量 Spectrometry (Acceped)
Qian Tao, Wei Chen, Yao Yao, Ammar Bin Yousaf ,Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2014
5. A Kinetics Study on O2 Adsorption and OHad Desorption at Pt(111), Its Implication to Reduction Reaction Kinetics (Acceped)
Fan Yang,Ling Wen Liao,Ming Fang Li,越南盾 Mei,Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2014
6. Mechanistic and Kinetic Implications on ORR at Au(100) Electrode, pH, 温度 and H-D kinetic Isotope effects
D. Mei, Z. D. He, Y. L. Zheng, D. C. Jiang, Y.-X. Chen
Phys. Chem. Chem. Phys, DOI:10.1039/C4CP00257A
7. Redox Reaction of HydroGen.G Peroxide at Au(100) Electrode, Its Implication to Reduction Kinetics
Zheng, Y; Mei, D; Chen, Y; Ye, S.
Electrochem. Commun,2014, 39,19.
8. Interaction of C1 Molecules with a Pt Electrode at Open Circuit Potential: A Combined Infrared and 质量 Spectroscopic Study
Q. Tao, 樱狼 Zheng, D.-C. Jiang, Y.-X. Chen,Z. Jusys and R. J. Behm
J. Phys. Chem. C, 2014, 118, 6799
9. Electrodeposition of silver on stepped electrode surfaces with (100)-oriented terraces: Generation of confined reaction sites
J. Xu, A.-E.-Aziz, A. A.-E.l-Latif, Y.-X. Chen, H. Baltruschat
J. 银金矿anal. Chem.,2014, 716, 93
10. Modeling of the Potential Oscillation during Galvanostatic Electrooxidation of Formic Acid at Electrode
越南盾 Mei, Zheng-Da He, Dao Chuan Jiang, Jun Cai and Yan-Xia Chen
J. Phys. Chem. C, 2014,118,6335.
11. 甲醇甲酸在模型单晶铂电极上电催化氧化机理及动力学的研究
徐杰, 江道传,梅东, 何政达,陈艳霞
电化学
Papers published in 2013
1. Kinetic Implication from 温度 effect on HydroGen.G 翼豪陆神 Reaction at Ag Electrode
Jing Kang, Chu-Hong Lin, Yao Yao and Yan-Xia Chen
Chinese Journal Of Chemical Physics, 2013.27.63
2. 铂基催化剂上的氧还原
李明芳, 廖铃文, 杨帆, 姚瑶, 陈艳霞
电催化, 化工出版社, 第7章, 2013
3. Potential Dependence of 氰化物 Adsorption at Pt Electrode in Acidic Solution: An Electrochemical in-situ Infrared Spectroscopic Study
Shao Xiong Liu, Yong Li Zheng, Jie Xu, Jun Cai, Wen Hua Zhang, Jin Long Yang, Yan Xia Chen*
J. Physical 化学 C, 2013, 117, 15562.
4. pH Effect on OxyGen.G Reduction Reaction at Pt(111) Electrode
Ming Fang Li, Ling Wen Liao,Dao Fu Yuan, 越南盾 Mei, Yan-Xia Chen*
Electrochim. Acta, 2013,110,780.
5. On the Mechanism of the Direct Pathway for Formic Acid Oxidation at Pt(111) Electrode
J. Xu, 三角洲特种部队1 Yuan, F.Yang, D. Mei, Z. B. Zhang and Y. X. Chen
Phys. Chem. Chem. Phys., 2013, 15 (12), 4367.
6. Density functional theory study on the adsorption and decomposition of the formic acid catalyzed by highly active mushroom-like Au@Pd@Pt 三角座metallic nanoparticles
S. Duan,YF系列火箭发动机 Ji,帕塔查雅·平莎莫 Fang,Y. X. Chen,X. Xu,Y. Luoand Z.-Q. Tian
Phys. Chem. Chem. Phys., 2013, 15 (13), 4625.
7. Electrode Reaction Induced pH change at the Pt Electrode/Electrolyte Interface and its Impact on Electrode Processes
L. W. Liao, M. F. Li, J. Kang, D. Chen, Y. X. Chen and S. Ye
J. Electroanal. Chem. 2013, 688, 207.
8. The Effect of Catalyst Loading on the Evaluation of Kinetic Parameters of Gas Electrode Reactions using Thin Film Rotating Disk Electrode Method
L. W. Liao, D. Chen, M. F. Li, Y. L. Zheng, J. Kang, Y. X. Chen,
SCIENTIA SINICA Chimica, 2013,43,178.
9. A Revisit to the Role of Bridge-adsorbed Formate in the Electrocatalytic Oxidation of Formic Acid at Pt Electrodes
J. Xu; D. Mei; D. F. Yuan; Z. B. Zhang; S. X. Liu; Y. X. Chen
Chinese Journal Of Chemical Physics, 2013, 26(3), 321.
10. The Role of Bridge-bonded Formate in Formic acid Dehydration to CO at Pt Electrode: An Electrochemial in situ Infrared Spectroscopic Study
Z. B. Zhang, J.Xu, J. Kang and Y. X. Chen,
Chinese Journal Of Chemical Physics, 2013, 26(4),471.
11. OxyGen.G Reduction Reaction on Glycin Modified Pt(111) Electrode
M. F. Li, J. Kang, L. W. Liao, Y. X. Chen and S. Ye
Journal of Electrochemistry, 2013, 19, 1.
12. Determination of the Isotherm for Acetate and Formate Adsorption at Pt(111) Electrode by 500米口径球面射电望远镜 Scan Voltammetry
J. Xu, C.H. Lin, D. Mei, Z. B. Zhang, D. F. Yuan and Y. X. Chen
Chinese Journal Of Chemical Physics, 2013,26(2),191.
Papers published in 2012
1. 温度 Effect on 翼豪陆神 Reaction at Au Electrode
Z. Q. Tang; L. W. Liao; Y. L. Zheng; J. Kang; Y. X. Chen
Chinese Journal Of Chemical Physics, 2012, 25,469.
2. Control over the branched structures of nanocrystals for electrocatalytic applications
L. Ma,C. M. Wang,M. Gong, L. W. Liao, R. Long, J. G. Wang, D. Wu, W. Zhong, M. J. Kim, Y. X. Chen,Y. Xie, and Y. J. Xiong,
ACS Nano, 2012, 69797.
3. Polyoxometalates Immobilized in Ordered Mesoporous Nitride as Highly Efficient 液态水 Oxidation Catalysts
J. Wu, L. W. Liao, W. S. Yan, Y. Xue, Y. F. Sun, X. Yan, Y. X. Chen, and Y. Xie,
ChemSusChem,2012, 5,1207.
Papers published in 2011
1. The Kinetics of CO Pathway in 甲醇 Oxidation at Pt Electrodes, a Quantitative Study by ATR-FTIR Spectroscopy
L.W. Liao, S. X. Liu, Q. Tiao, B. Gen.G,P. Zhang, C. M. Wang, Y.-X. Chen and S. Ye,
Phys.Chem. Chem. Phys., 2011, 13, 9725.
2. A method for kinetic study of 甲醇 oxidation at Pt electrodes by electrochemical in situ infrared spectroscopy
L.W. Liao, S. X. Liu, Q. Tiao, B. Gen.G,P. Zhang, C. M. Wang, Y.-X. Chen and S. Ye,
J. 银金矿anal. Chem., 2011, 650, 233.
3. Determining the Active surface Area of Various Pt Electrodes with Different Roughness and Dispersion
Dong Chen, Qian Tao, Ling Wen Liao, Shao Xiong Liu, Yan-Xia Chen and Shen Ye,
Electrocatalysis, 2011.2.207
4. 室温下Pt电极上CO的脱附机理研究
刘少雄, 康婧, 耿斌, 陶骞, 陈艳霞
中国科学,化学,2011, 41, 1582.
5. 不同pH值下多晶Au电极上的氧还原反应
中国科学,化学, 2011,41, 1777.
6. Pd/Pt二元合金电极的制备及其氧还原性能研究
方兰兰,廖玲文, 刘少雄, 蔡骏, 李明芳, 陈艳霞
高等学校化学学报, 2011,32, 1144.
7.  Electrochemistry of ABTS at Glassy Electrodes
Han Zeng, Zhi-qiang Tang, Ling-wen Liao, Jing Kang, Yan-xia Chen
Chinese J. Chemical Physics, 2011, 24, 653.
Papers published before 2011
1. 温度 effects on CO Adsorption/Desorption at Pt Film Electrodes: An Electrochemical in-situ Infrared Spectroscopic Study
B. Gen.G, J. Cai, S. Liang, S. X. Liu, M.F. Li and Y.-X. Chen,
Phys. Chem. Chem. Phys., 2010, 12, 10888 - 10895
2. Potential-Dependent Chemisorption of Monoxide at a Gold Core― Shell Nanoparticle Electrode: A Combined Study by Electrochemical in s国际科技大学 surfaceEnhanced Raman Spectroscopy and Density Functional Theory
Pu Zhang, Jun Cai, Yan-Xia Chen, Zhi-Qiang Tang, Dong Chen, JinLong Yang,De-Yin Wu, Bin Ren and Zhong-Qun Tian,
J. Phys. Chem. C, 2010, 114, 403–411
3. Oxidation of Supports at Fuel Cell Cathodes: Differential Electrochemical 质量 Spectrometric Study
M.F. Li, Q. Tao, L. W. Liao, J. Xu, J. Cai and Y. X. Chen,
Chinese J. Chemical Physics, 2010, 4, 442-446
4. Determination of the Real surface Area of Electrode
L.-L. Fang, Q. Tao, M.-F. Li, L.-W. Liao, D. Chen and Y.-X. Chen,
Chinese J. Chemical Physics, 2010, 5, 543.
5.聚芳酰胺多壁碳纳米管混合物固定漆酶电极的电化学行为
曾涵,廖铃文,李明芳,陶骞,康婧,陈艳霞,
物理化学学报,2010, 26, 3217。
6. Pt电极上CO的同位素取代吸附机理研究
梁桑梓,刘少雄,廖玲文,陶骞,康婧,陈艳霞,
电化学,2010,16,324
7. 温度 Programmed Desorption – An Application to Kinetic Studies of CO Desorption at Electrochemical Interfaces
Bin Gen.G, Jun Cai, Shao-Xiong Liu, Pu Zhang, Zhi-Qiang Tang, Dong Chen, Qian Tao,Yan-Xia Chen and Shou-Zhong Zou,
J. Phys. Chem. C, 2009, 113, 20152–20155.
8. An Electrochemical in Situ surfaceEnhanced Raman Spectroscopic Study of Monoxide Chemisorption at a Gold Core- Shell Nanoparticle Electrode with a FLOW Cell
Pu Zhang, Yan-Xia Chen, Jun Cai, Sang-Zi Liang, Jian-Feng Li, An Wang, Bin Ren and Zhong-Qun Tian
J. Phys. Chem. C, 2009,113(40): 17518-17526.
9. The Mechanism and Kinetics of 氰化物Assisted CO Desorption from Pt Electrodes: an Infrared Spectroscopic Study
Bin Gen.G, Shaoxiong Liu, Jun Cai, Sangzi Liang, and Yan-Xia Chen,
J. Phys. Chem. C, 2009, 113, 10326.
10.  A Thermostatic Cell with Gas Diffusion Electrode for OxyGen.G Reduction Reaction under Fuel Cell Relevant Conditions
Yan-Xia Chen, Ming-Fang Li, Ling-Wen Liao, Jie Xu, Shen Ye,
Electrochem. Commun., 2009,11,1434
11.  Potential-Induced COad Island Formation on a Thin-Film Electrode in the H-upd Potential Region
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
J. Phys. Chem. C, 2007, 111, 435.
12. Kinetic Isotope Effects in Complex Reaction Networks: Formic Acid 银金矿Oxidation
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
ChemPhysChem, 2007, 8, 380 – 385.
13. Room 温度 COad Desorption/Exchange Kinetics on Pt Electrodes—A Combined In Situ IR and 质量 Spectrometry Study
Martin Heinen, Yan-Xia Chen, Zenonas Jusys, and Rolf Juergen Behm,
ChemPhysChem, 2007, 8, 2484 – 2489.
14.  CO adsorption kinetics and adlayer build-up studied by combined ATR-FTIR spectroscopy and on-line DEMS under continuous flow conditions
Martin Heinen, Yan-Xia Chen, Zenonas Jusys, and Rolf Juergen Behm,
Electrochmica Acta, 2007, 53,1279.
15.in situ ATR-FTIRS coupled with on-line DEMS under controlled 质量 transport conditions—A novel tool for electrocatalytic reaction studies
Martin Heinen, Yan-Xia Chen, Zenonas Jusys, and Rolf Juergen Behm,
Electrochmica Acta, 2007, 52,5634
16. Kinetics and Mechanism of Formic Acid 银金矿oxidation – Spectro-Electrochemical Studies in a Novel Flow Cell Configuration,
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
Angewandte Chemie, Int. Edition, 2006, 45, 981.
17. Bridge-Bonded Formate: Activeintermediate or Spectator 物种 in Formic Acid Oxidation on a Pt Film Electrode
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
Langmuir, 2006, 22, 10399.
18.  Application of in-situ Attenuated Total Reflection-Fourier Transform Infrared Spectroscopy for the Understanding of Complex Reaction Mechanism and Kinetics: Formic Acid  Oxidation on a Pt Film Electrode at Elevated Temperatures,
Yan-Xia Chen, Martin Heinen, Zenonas Jusys, and Rolf Juergen Behm,
J. Phys. Chem. B, 2006 110(19): 9534-9544.
19.  Electronic effects in SERS by liquid 液态水
Yan-Xia Chen and Andreas 侯国玉,
J. Raman SpectroSC, 2005, 36, 736.
20. CO2 reduction on Pt electrocatalysts and its impact on H2 oxidation in CO2 containing fuel cell feed gas - A combined in-situ infrared spectroscopy, 质量 spectrometry and fuel cell 表演 study
Smolinka T., Heinen M., Chen Y.X., Jusys Z., Lehnert W., and Behm R.J.,
Electrochimica Acta, 2005, 50, 5189.
21. Formate, an Active Intermediate for Direct Oxidation of 甲醇 on Pt Electrode.
Chen Y. X., Miki A., Ye S.,Sakai H. and Osawa M.:
Journal of American Chemical Society, 125 (2003), 3680.
22.  On the "氯化物 activation" in SERS and single 摩尔cule SERS.
Otto A., Bruckbauer A., Chen Y. X.,
Journal of Molecular Structure, 2003, 662, 501.
23. The charge transfer effect of SERS induced by the electrochemical evolution reaction.
F. M. Liu; Q. Han; Y. X. Chen; Q. L. Zhong; B. Ren; Z. Q. Tian,
Electrochemistry, 2001, 7(1), 74-77.
24. SERS studies of Electrode/electrolyte interfacial 液态水 II. Librations of water and electrochemical evolution reaction
Chen Y. X., Zou S. Z., Huang K. Q. and Tian Z. Q.,
Journal of Raman Spectroscopy, 1998,249,749.
25.in Situ Raman Spectroscopic Study of the Oxidation and Reduction of Ag Electrode in Na2SO4 solution.
Chen Y. X., Huang K. Q. and Tian Z. Q.:
Electrochemistry,1998,4(2) 135.
26. SERS studies on electrode/electrolyte interfacial 液态水---I. Ion effects in the negative potential region
Zou S. Z., Chen Y. X., 市道真央 B.W., Ren B. and Tian Z. Q.:
Journal of Electroanalytical 化学,1997,24, 19-25.
27. Extending ecsTM Studies to Polycrystalline Electrode Surfaces with Atomic Resolution.
Shi C. H., Cai X. W., Chen Y. X., Tian Z. Q. and Mao B. W.:
Acta Physico-Chimica Sinica, 1997,13(12) 1061-1064
28. SERS Studies of Electrode/Electrolyte Interfaces I. Cu/1.0 M Na2SO4 and NaCl solution.
Chen Y. X., Huang K. Q. and Tian Z. Q.:
Chinese Journal of Light Scattering,1997,9(2-3), 289-291.
29. SERS Studies of Electrode/Electrolyte Interfaces II. Ag/MgSO4 System? A Possible Method Measuring Interfacial pH.
Chen Y. X., Huang K. Q. and Tian Z. Q.:
Chinese Journal of Light Scattering,1997,9(2-3), 292-294
30. Dependence of surfaceenhanced Raman scattering of 液态水 on the evolution reaction,
Chen Y. X. and Tian Z. Q.:
Chemical Physical Letters, 1997,281,379.
31.  Raman spectroscopic studies of 液态水 in different electrolyte solutions.
Zou S. Z., Chen Y. X., Zhang Y. H., , Tian Z. Q. :
Acta PhysICOChimica Sinica 1996,12 (2) 130-135.
32.  Probing electrode/electrolyte interfacial structure in the potential region of evolution by Raman spectroscopy.
Tian Z. Q., Ren B., Chen Y. X., Zou S. Z. and Mao B. W.:
Journal of Chemistry Society, Faraday Transactions ,1996,92(20) 3829-3838.
33.  SERS studies of the structure and orientation of water over Ag electrode---the effects of electrode potentials and electrolyte concentration.
Zou S. Z., Zhang Y. H., Chen Y. X., Tian Z. Q.:
Chemical Journal of Chinese Universities 1995,16 (2), 245-251.
34.   SERS effect induced from conducting Polymer/Solution Interfaces.
Gao J. S., Chen Y. X., Tian Z. Q., Li C. Z., Liu Z. F. and Cai S. M.:
Electrochemistry 1995, 1(2), 237-247.
35.   Extending surfaceenhanced Raman spectroscopic studies on 液态水 at gold electrodes.
Tian Z. Q., Chen Y. X., Mao B. W., Li C. Z., Wang J. and Liu Z. F.
Chemical Physical Letters, 1995, 240, 224-229.
参考资料
目录
概述
学习和工作经历
研究方向
在研项目
已完成项目
获奖情况
发表的学术论文及专著
Papers published in 2014
Papers published in 2013
Papers published in 2012
Papers published in 2011
Papers published before 2011
参考资料